1st of all, the larger the bore - at least with lead projectiles, the better the POTENTIAL accuracy as minor defects effect larger heavier projectiles less than they do smaller projectiles.
2ndly, with air rifles, longer bullets in any calibre size to produce higher SD's and BC's generate more internal bore friction - in order to get higher numbers in smaller bores, the bulelts become excessively long.
This is easier to "see" in extremes.
Thus, it is easy to obtain Sectional density of .238, just from a relatively short-for-.45cal. 350gr. bullet. The BC would be approximately .200.
To get these numbers in a .22cal. - well, you can't as the 'bullet' would have to be over 70gr. as at that weight, the SD is only .199 with a BC of .200 for a smooth sided jacketed bullet.
We do know, if the BC's are the same and the velocities are the same, the trajectories & wind drift will also be identical.
It is just easier to get higher, useable numbers in larger calibres.
FYI, In CF rifles, recoil comes into the equation, thus you will see .308 calibres about max. for long range accuracy. Thus, the current record at 1000 yard record is 5 shots in 1.403", shot with a .308 calire rifle.
http://bulletin.accurateshooter.com/200 ... 000-yards/During the civil war and decades following, long range muzzleloading match rifles ran upwards of .60 calibre and today, lead bullet shooting muzzleloading rifles run to .69 calibre. These are mostly used for shooting from 100 to 300yards.